Kinetic equations for thermal degradation of polymers

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Kinetic equations for thermal degradation of polymers

Kinetic equations are analyzed for thermal degradation of polymers. The governing relations are based on the fragmentation–annihilation concept. Explicit solutions to these equations are derived in two particular cases of interest. For arbitrary values of adjustable parameters, the evolution of the number-average and mass-average molecular weights of polymers is analyzed numerically. Good agree...

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ژورنال

عنوان ژورنال: Modelling and Simulation in Materials Science and Engineering

سال: 2004

ISSN: 0965-0393,1361-651X

DOI: 10.1088/0965-0393/12/4/002